A Ukrainian separatist leader is calling on Russia to "absorb" the eastern region of Donetsk after Sunday's referendum on self-rule.
Denis Pushilin, leader of the self-declared Donetsk People's Republic, said Moscow should listen to the "will of the people".
Russia has called for dialogue and "implementing" the result, but Ukraine and the EU declared the poll illegal.
The EU is imposing further sanctions over Russia's actions in Ukraine.
Separatists in Donetsk and Luhansk regions say 89% and 96% respectively voted in favour of "self-rule".
Mr Pushilin said that Ukrainian presidential elections, scheduled to take place on 25 April, would not happen in Donetsk because it was now "independent".
He added that he was not calling for Russian military intervention but that peacekeepers may be needed.
The region would switch to the Russian currency, the rouble, he said.
Earlier the head of the rebel Donetsk election commission, Roman Lyagin, said joining Russia "would probably be an appropriate step".
Russia has called for dialogue between the militants and Kiev with the participation of the Organisation for Security and Co-operation in Europe.
Two Crimean companies and 13 individuals have been added to the sanctions list - the names are likely to be announced officially within the next 24 hours, reports the BBC's Chris Morris in Brussels.
The sanctions impose travel bans and asset freezes. EU ministers are also discussing what might trigger a broader package of sanctions against the Russian economy.
In a brief statement, the Kremlin denounced what it claimed had been "attempts to disrupt the votes, with the use of force, including the use of heavy weapons, against civilians", says the BBC's Steve Rosenberg in Moscow.
The Russian authorities said they expected the results of the vote to be implemented in a civilised manner, without any repetition of violence and called for dialogue between Kiev, Donetsk and Luhansk.
Later Russia's Foreign Minister, Sergei Lavrov, said there were no plans to hold fresh international talks on the crisis - he accused the West of an "information blockade" over events in Ukraine and of "shameless lies".
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